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Material Safety Data Sheet

TRADE NAME (COMMON NAME):

PROPELLANT 49 DE-ICER

 

CAS NUMBER:

10043-52-4 (anhydrous)

 

MOLECULAR WEIGHT:

110.99

PACE PRODUCTS, INC

4510 W89 TH ST

PRAIRIE VILLAGE KS 66207

 

CONTACT:

PACE PRODUCTS, INC

PHONE NUMBER:

913-469-5588

LAST ISSUE DATE:

October, 2003

CURRENT ISSUE DATE:

OCTOBER, 2013



 

EMERGENCY PHONE NUMBER:

888-389-8203

EYES:

Flush promptly with plenty of water, continuing for at least 15 minutes.  Get medical attention.

 

SKIN:

Wash with plenty of water.

 

INHALATION:

Remove to fresh air.

 

INGESTION:

If conscious, immediately give 2 to 4 glasses of water, and induce vomiting by touching finger to back of throat. 

 

 

Get medical attention for irritation, ingestion, or discomfort from inhalation.





INHALATION:

Vapors are unlikely due to physical properties. Mists may cause irritation to the upper respiratory tract.

 

INGESTION:

Single dose, oral toxicity is believed to be low. Ingestion may cause gastrointestinal irritation and ulceration.

 

SKIN:

Short, single exposure is not likely to cause significant skin irritation. Prolonged or repeated exposure may cause skin irritation, even a burn. May cause more severe response if confined to skin or skin is abraded. A single, prolonged exposure is not likely to result in material being absorbed through the skin in harmful amounts.

 

EYES:

May cause moderate to severe eye irritation with corneal injury, which may be slow to heal.

 

PERMISSIBLE CONCENTRATION: AIR

(SEE SECTION J)

 10 mg/m3 – nuisance dust 

BIOLOGICAL

None

UNUSUAL CHRONIC TOXICITY:

None.


FLASH POINT:

Not flammable

 

OPEN CUP  FORMCHECKBOX                         CLOSED CUP  FORMCHECKBOX

AUTO IGNITION

TEMPERATURE

NA

FLAMMABLE LIMITS IN AIR (% BY VOL.)

 

LOWER - NA               UPPER - NA

UNUSUAL FIRE AND EXPLOSION HAZARDS

 

See hazard of contact with zinc as in galvanized iron: Section G.

 



FIRE EXTINGUISHING AGENTS RECOMMENDED:

NA

 

FIRE EXTINGUISHING AGENTS TO AVOID:

NA

 

SPECIAL FIREFIGHTING PRECAUTIONS:

Use positive pressure, self-contained breathing apparatus.

 

VENTILATION:

Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines.

 

NORMAL HANDLING:

Avoid contact with eyes, skin or clothing.  Avoid breathing mist.  Use good personal hygiene and housekeeping.

 

STORAGE:

Store in a cool, dry area.  Prolonged storage may cause product to cake and become wet from atmospheric moisture.

 

SPILL OR LEAK (ALWAYS WEAR PERSONAL PROTECTIVE QUIPMENT – SECTION E)

Shovel up dry chemical and place in metal drum with a cover.  Cautiously spray residue with plenty of water.

 

SPECIAL: PRECAUTIONS/PROCEDURES/LABEL INSTRUCTIONS:


SIGNAL WORD

WARNING!


RESPIRATORY PROTECTION:

For dusty or misty condition, wear NIOSH-approved air-purifying respirator.

 

 

EYES AND FACE:

Safety goggles. Face shield and chemical goggles for extensive exposure. Under these conditions, do not wear contact lenses.

 

 

HANDS, ARMS, AND BODY:

As a minimum, wear long-sleeve shirt and trousers or coveralls, boots, and gloves for routine product use.

Cotton gloves permitted for dry product, impervious gloves when using solutions.

 

 

OTHER CLOTHING AND EQUIPMENT:

Eye-wash facility.

 

 

 

 


MATERIAL IS AT NORMAL CONDITIONS:

 

LIQUID   FORMCHECKBOX    SOLID  FORMCHECKBOX    GAS  FORMCHECKBOX

 

 FORMCHECKBOX   _____________________

APPEARANCE AND COLOR:

White to off white solid pellets; odorless.

BOILING POINT:                         Unknown °C

 

MELTING POINT:                        772 °C

 

SPECIFIC GRAVITY:  

(H2O = 1)                            

                                  2.26 g/cc @ 20° C

                                          

VAPOR DENSITY:

(AIR =1)

                                 NA: water vapor only.     

 

SOLUBILITY IN WATER:

(% BY WEIGHT)

                             Very soluble

pH:

                   Neutral or slightly alkaline

                          

VAPOR PRESSURE:

(mm Hg @ 20°C)    FORMCHECKBOX     (PSIG)  FORMCHECKBOX

               NA

 

EVAPORATION RATE:

(Butyl acetate=1)   FORMCHECKBOX     (Ether = 1.0)   FORMCHECKBOX

                          NA

 

% VOLATILES BY VOLUME:

(AT 20°C)

                                 NA

 






STABILITY:

 

UNSTABLE  FORMCHECKBOX        STABLE  FORMCHECKBOX

 

CONDITIONS TO AVOID:

 

                             NA

INCOMPATIBILITY (MATERIALS TO AVOID):

Sulfuric acid: yields hydrogen chloride gas, which is corrosive, irritating, and reactive.  Water-reactive materials, such as sodium: cause an exothermic reaction.  Methyl vinyl ether: starts runaway polymerization reaction. Zinc as in galvanized iron: yields hydrogen gas with solutions, which may explode under these conditions.

 

HAZARDOUS DECOMPOSITION PRODUCTS:

 

Fumes of chloride ( Cl- ) are given off at temperatures above 1600 °C.

 

HAZARDOUS POLYMERIZATION:

 

MAY OCCUR     FORMCHECKBOX           \

WILL NOT OCCUR    FORMCHECKBOX

 

CONDITIONS TO AVOID:

 

                NA





STABILITY:

 

UNSTABLE  FORMCHECKBOX        STABLE  FORMCHECKBOX

 

CONDITIONS TO AVOID:

 

                             NA

INCOMPATIBILITY (MATERIALS TO AVOID):

Sulfuric acid: yields hydrogen chloride gas, which is corrosive, irritating, and reactive.  Water-reactive materials, such as sodium: cause an exothermic reaction.  Methyl vinyl ether: starts runaway polymerization reaction. Zinc as in galvanized iron: yields hydrogen gas with solutions, which may explode under these conditions.

 

HAZARDOUS DECOMPOSITION PRODUCTS:

 

Fumes of chloride ( Cl- ) are given off at temperatures above 1600 °C.

 

HAZARDOUS POLYMERIZATION:

 

MAY OCCUR     FORMCHECKBOX           \

WILL NOT OCCUR    FORMCHECKBOX

 

CONDITIONS TO AVOID:

 

                NA





DEGRADABILITY/AQUATIC TOXICITY:

 

 

OCTANOL/WATER PARTITION COEFFICIENT

                               NA

 

Aquatic Toxicity: TLm96: over 1000 ppm

 

EPA HAZARDOUS SUBSTANCE?

(CLEAN WATER ACT SECT. 311)          YES   FORMCHECKBOX      NO   FORMCHECKBOX           IF SO, REPORTABLE QUANTITY:

 

40 CFR

116-117

WASTE DISPOSAL METHODS (DISPOSER MUST COMPLY WITH FEDERAL, STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS):

 

Treatment or disposal of waste generated by use of this product should be reviewed in terms of applicable federal, state and local laws and regulations.  Users are advised to consult with appropriate regulatory agencies before discharge, treatment or disposal.

 

 

 

RCRA STATUS OF UNUSED MATERIAL IF DISCARDERD:

Not a “hazardous waste”.

HAZARDOUS WASTE NUMBER: (IF APPLICABLE)

                                 --

40 CFR

261

 






PERMISSIBLE CONCENTRATIONS REFERENCES:

 

 

None.

 

 

REGULATORY STANDARDS

 

DOT CLASSIFICATION:

              Not regulated

49 CFR

173

 

 

None.

 

 

 

GENERAL: